Rearrangement, nucleophilic substitution, and halogen switch reactions of alkyl halides over NaY Zeolite: formation of the bicyclobutonium cation inside the zeolite …

M Franco, N Rosenbach, GB Ferreira…

Index: Franco, Marcelo; Rosenbach Jr., Nilton; Ferreira, Glaucio B.; Guerra, Antonio C. O.; Kover, W. Bruce; Turci, Cassia C.; Mota, Claudio J. A. Journal of the American Chemical Society, 2008 , vol. 130, # 5 p. 1592 - 1600

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Citation Number: 25

Abstract

Rearrangement and nucleophilic substitution of cyclopropylcarbinyl bromide over NaY and NaY impregnated with NaCl was observed at room temperature. The first-order kinetics are consistent with ionization to the bicyclobutonium cation, followed by internal return of the ...

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