Stereoselective Synthesis of 4??Dehydroxydiversonol Employing Enantioselective Palladium??Catalysed Domino Reactions

LF Tietze, DA Spiegl, F Stecker, J Major…

Index: Tietze, Lutz F.; Spiegl, Dirk A.; Stecker, Florian; Major, Julia; Raith, Christian; Grosse, Christian Chemistry - A European Journal, 2008 , vol. 14, # 29 p. 8956 - 8963

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Citation Number: 49

Abstract

Abstract The stereoselective synthesis of 4-dehydroxydiversonol (4) employing enantioselective palladium-catalysed domino processes such as the domino Wacker–Heck and the domino Wacker-carbonylation reaction for the formation of the central chroman moiety is described. Thus, reaction of 8 with palladium (II) trifluoroacetate [Pd (OTFA) 2] in the presence of carbon monoxide, methanol and the 2, 2′-bis (oxazolin-2-yl)-1, 1'- ...

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