Synthesis

Palladium-catalyzed silastannation of secondary propargylic alcohols and their derivatives

TE Nielsen, S Le Quement, D Tanner

Index: Synthesis, , # 9 p. 1381 - 1390

Full Text: HTML

Citation Number: 20

Abstract

... The reaction products are valuable intermediates in the synthesis of tri- and tetrasubstituted alkenes, eg via subsequent metal-catalyzed ... to the α-position of the alkoxy group using Ito's catalyst [Pd(OAc) 2 /tert-alkyl isocyanide], [9] or to the β-position via Pd(Ph 3 P) 4 catalysis. ...

Related Articles:

A simple and efficient hydrolyzing method for tetrahydropyranyl ethers

[Tetrahedron Letters, , vol. 40, # 7 p. 1323 - 1326]

Synthesis of Fatty Acids with Smooth Muscle Stimulant Activity

[Journal of Medicinal Chemistry, , vol. 8, p. 41 - 45]

A novel, highly efficient and selective desilylating method for trialkylsilyl ethers

[Tetrahedron Letters, , vol. 39, # 29 p. 5249 - 5252]

Gold-catalyzed ethynylation of arenes

[Journal of the American Chemical Society, , vol. 132, # 5 p. 1512 - 1513]

Enantioselective synthesis of both enantiomers of various propargylic alcohols by use of two oxidoreductases

[European Journal of Organic Chemistry, , # 22 p. 4181 - 4187]

More Articles...