Development of technique for synthesis of methyl (β-oxyethyl) sulfide by the reaction of ethylene oxide with methyl mercaptan

OI Tuzhikov, TV Khokhlova, SB Zotov…

Index: Tuzhikov; Khokhlova; Zotov; Orlova Russian Journal of Applied Chemistry, 2011 , vol. 84, # 4 p. 632 - 639

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Abstract

Abstract Reaction of ethylene oxide with methyl mercaptan in the presence of a catalyst, a solution of potassium hydroxide in methyl (β-oxyethyl) sulfide, was studied. Various technological procedures for synthesis of methyl (β-oxyethyl) sulfide were analyzed. The process conditions providing a 98–99% conversion of the starting reagents at a selectivity of 97–98% were suggested.

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