Tetrahedron

Solvent influences on initial and transition states in solvolysis of 2-chloroethyl methyl sulfide

MR Sedaghat-Herati, JM Harris, SP McManus

Index: Sedaghat-Herati, M. R.; Harris, J. M.; McManus, S. P. Tetrahedron, 1988 , vol. 44, # 24 p. 7479 - 7488

Full Text: HTML

Citation Number: 0

Abstract

Nucleophilic substitution reactions of 2-(alkylthio) ethyl derivatives have become important in understanding basic principles of physical organic chemistry. In the present work the solvent effects of 2-chloroethyl methyl sulfide (1-Cl) solvolysis in methanol, methanol-water mixtures, and water are analyzed to provide a dissection of initial-state (IS) and transition- state (TS) effects. The reduction in activation energy accompanying replacement of ...

Related Articles:

Development of technique for synthesis of methyl (β-oxyethyl) sulfide by the reaction of ethylene oxide with methyl mercaptan

[Tuzhikov; Khokhlova; Zotov; Orlova Russian Journal of Applied Chemistry, 2011 , vol. 84, # 4 p. 632 - 639]

Intramolecular sulfur-assisted NaBH 4 reduction of esters synthesis of 5-oxo-ETE and 5-oxo-12-HETE

[Khanapure, Subhash P.; Saha, Goutam; Sivendran, Sashikala; Powell, William S.; Rokach, Joshua Tetrahedron Letters, 2000 , vol. 41, # 30 p. 5653 - 5657]

Silica–PSCl3: A Mild and Efficient Reagent for Deoxygenation of Sulfoxides

[Pandey, Lokesh Kumar; Pathak, Uma; Rao, A. Narasimha Synthetic Communications, 2007 , vol. 37, # 23 p. 4105 - 4109]

THE EFFECT OF STRUCTURE OF ORGANIC HALIDES ON THEIR RATE OF REACTION WITH INORGANIC HALIDES. II. THE EFFECT OF THE METHYLTHIO …

[Kirner Journal of the American Chemical Society, 1928 , vol. 50, p. 2452]

Efficient and/or selective methylation by diazomethane of alcohols, halo alcohols, glycols, amino alcohols and mercapto alcohols with the use of a proton??exchanged …

[Takeuchi, Hiroshi; Kishioka, Hiroaki; Kitajima, Kunio Journal of Physical Organic Chemistry, 1995 , vol. 8, # 2 p. 121 - 126]

More Articles...