Tetrahedron

The non-reaction of methylene with the carbon-carbon bond

G Wu, M Jones, W von E Doering, LH Knox

Index: Wu, Guo-Xian; Maitland Jr., Jones; Doering, William von E.; Knox, Lawrence H. Tetrahedron, 1997 , vol. 53, # 29 p. 9913 - 9920

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Citation Number: 11

Abstract

However, it quickly became clear that something was awry, because, as noted by Frey and his collaborators very early on,[7]and explicitly recognized by Shechter,[6]the thermal decompositions of these precursors gave the same two products in a very different ratio (∼(10:90). It is now clear that the products of “carbon-carbon insertion” formed through intramolecular reactions in simple photolyses of diazo compounds owe their existence mainly to reactions of photo-excited ...

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