Synthesis of Substituted Aminogallanes by Alkyltrimethyltin Elimination

WR Nutt, KJ Murray, JM Gulick, JD Odom, Y Ding…

Index: Nutt, W. Rodger; Murray, Kelly J.; Gulick, James M.; Odom, Jerome D.; Ding, Yan; Lebioda, Lukasz Organometallics, 1996 , vol. 15, # 6 p. 1728 - 1733

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Citation Number: 16

Abstract

The alkyltrimethyltin elimination reaction of R3Ga (R= Me, Et) with R''R'NSnMe3 (R''= i-Bu, SnMe3, C6H11 and R'= i-Bu, i-Pr, C6H11) has been found to afford a convenient, single- step, low-temperature pathway to [Me2GaN (i-Bu) 2] 2,[Et2GaN (i-Bu2)] 2,[Me2GaN (i-Pr) SnMe3] 2,[Me2GaN (C6H11) 2] 2, and [Et2GaN (C6H11) 2] 2.