Linking metal centres with diimido ligands: synthesis, electronic and molecular structure and electrochemistry of organometallic ditungsten complexes [{WCl 2 (Ph 2 …

DG Humphrey, MV Lee, SP Redmond

Index: Hogarth, Graeme; Humphrey, David G.; Kaltsoyannis, Nikolas; Kim, Woo-Sung; Lee, Mo-Yin; Norman, Tim; Redmond, Simon P. Journal of the Chemical Society - Dalton Transactions, 1999 , # 16 p. 2705 - 2723

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Citation Number: 10

Abstract

Tungsten () diimido-bridged complexes [{WCl (PhPMe)(CO)}(µ-N–X–N)] have been prepared oxidative addition of diisocyanates to two equivalents of [WCl (PhPMe)].- Substituted monoimido complexes [WCl (PhPMe)(CO)(NCHX-)](X= I, Br or C [[triple bond, length half m-dash]] CPh) have also been prepared but attempts to couple the X= I complex as a route to di