Facile Synthesis of β-Keto Esters from Methyl Acetoacetate and Acid Chloride: The Barium Oxide/Methanol System1

Y Yuasa, H Tsuruta, Y Yuasa

Index: Organic Process Research and Development, , vol. 2, # 6 p. 412 - 414

Full Text: HTML

Citation Number: 23

Abstract

... using barium oxide as a base component and then cleavage with an alcohol (MeOH) led to the β-keto ester in good yield, and we now report a process for the ... This procedure was similar to that described above. ... (3) Shriner, RL; Schmidt, AG; Roll, LJ Organic Syntheses; Wiley ...

Related Articles:

Synthesis of β-keto esters by carbonylation of halomethylketones

[Synthesis, , # 3 p. 317 - 319]

A New Mild Method for the C-Acylation of Ketone Enolates. A Convenient Synthesis of β-Keto-Esters,-Thionoesters, and-Thioesters

[Organic Letters, , vol. 15, # 2 p. 370 - 373]

Synthesis of β-keto esters by carbonylation of halomethylketones

[Synthesis, , # 3 p. 317 - 319]

Synthesis of β??Keto Esters Promoted by Yttria??Zirconia Based Lewis Acid Catalyst

[Synthetic Communications, , vol. 34, # 6 p. 1117 - 1123]

Versatile. beta.-ketoester and. beta.-ketonitrile synthesis through sulfide contraction

[Journal of Organic Chemistry, , vol. 46, # 16 p. 3230 - 3234]

More Articles...