The Journal of organic chemistry

Synthesis of Acyclic Ketones by Catalytic, Bidirectional Homologation of Formaldehyde with Nonstabilized Diazoalkanes. Application of a Chiral Diazomethyl ( …

AJ Wommack, JS Kingsbury

Index: Deur, Christopher J.; Miller, Michael W.; Hegedus, Louis S. Journal of Organic Chemistry, 1996 , vol. 61, # 8 p. 2871 - 2876

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Citation Number: 15

Abstract

... J. Org. ... Propargylic carbonyls perhaps best illustrate this fact since they are especially prone to Michael addition and subsequent heterocyclization. ... with Distinct Hydrazine Reagents. Further optimization of the carbonyl-to-diazo interchange was carried out with (S)-citronellal as a ...

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