Synthesis of aryloxyacetaldehydes and N-(aryloxyethyl) cyclohexanamine hydrochloroides

DS Shapenova, MK Belyatskii…

Index: Shapenova; Belyatskii; Panicheva Russian Journal of Organic Chemistry, 2010 , vol. 46, # 7 p. 1017 - 1020

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Abstract

Abstract Oxidation of 2-(aryloxymethyl) oxiranes with periodic acid gave a series of aryloxyacetaldehydes which reacted with cyclohexylamine in THF, and subsequent reduction of Schiff bases thus obtained with sodium tetrahydridoborate resulted in the formation of the corresponding secondary amines which were isolated and characterized as hydrochlorides.

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