Synthesis and Characterisation of Macrobicyclic Tetrathiafulvalene??Bridged Cage Molecules

…, N Svenstrup, J Rault??Berthelot, A Riou…

Index: Blanchard, Philippe; Svenstrup, Niels; Rault-Berthelot, Joelle; Riou, Amedee; Becher, Jan European Journal of Organic Chemistry, 1998 , # 9 p. 1743 - 1757

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Citation Number: 13

Abstract

Abstract A series of new macrobicyclic tetrathiafulvalenophanes of type 1 and 2 with three tetrathiafulvalene bridges has been prepared under high-dilution conditions using a stepwise selective protection-deprotection of tetrathiafulvalenethiolates. All the macrobicyclic tetrathiafulvalenes, along with the intermediate compounds 5 and 6 and the unexpected tetrathiafulvalene pentamers 17, were studied by cyclic voltammetry. An ...

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