A new glucosinolate synthesis

TH Keller, LJ Yelland, MH Benn

Index: Keller, Thomas H.; Yelland, Lois J.; Benn, M. H. Canadian Journal of Chemistry, 1984 , vol. 62, p. 437 - 440

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Citation Number: 12

Abstract

The tert-butyldimethylsilyl nitronate derived from 1-nitropropane was condensed with 2, 3, 4, 6-tetra-O-acetyl-β-d-glucopyranosylthiol to yield two geometrically isomeric thiohydroximates; the Z-isomeric form was then converted by conventional procedures into potassium ethylglucosinolate (" glucolepidiin").

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