Synthesis and electronic properties of triply bonded hexakis (fluoroalkoxy) dimolybdenum complexes. Structure of Mo2 [OCMe (CF3) 2] 6 and investigation of the …

TM Gilbert, AM Landes, RD Rogers

Index: Gilbert, Thomas M.; Landes, Arden M.; Rogers, Robin D. Inorganic Chemistry, 1992 , vol. 31, p. 3438 - 3444

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Citation Number: 24

Abstract

The compound “MoC13 (dme)”(dme= 1, Zdimethoxyethane) was prepared in pure form and formulated as the dimeric Mo2C16 (dme) 2 (1). This material proved an excellent starting material for the metathetical syntheses of metal-metal triply bonded M02X6 complexes, including the hexaalkyls MO~(CH~ MM~))~(M= C (6), Si (7)), the hexaalkoxides Mo2 (0CMe2CH2R)(R= H (2), Me (3)), and the new hexakis (fluoroa1koxide) dimers Mo~[~ CM ...