Fe (III) complexes of a bis-benzimidazolyl diamide ligand: Spectral and Catalytic studies

G Ahuja, P Mathur

Index: Ahuja, Gauri; Mathur, Pavan Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2011 , vol. 83, # 1 p. 180 - 186

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Abstract

A new tetradentate bis benzimidaozlyl diamide ligand N, N′-Bis (benzimidazol-2-yl-methyl)- hexane-1, 6-dicarboxamide (GBSA) has been synthesized and utilized to prepare new Fe (III) complexes with exogenous anionic ligand X= Cl− and NO3−. Isomer shift values are in the range found for Iron in the+ 3 oxidation state while Quadrupole Splitting indicates large distortion from a six coordinate geometry, a finding supported by low temperature EPR ...

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