Bridged polycyclic compounds. 85. Cationic rearrangements accompanying heterolysis of 7-dibenzobicyclo [2.2. 2] octadienylcarbinyl derivatives

SJ Cristol, GO Mayo, JP Kochansky

Index: Cristol,S.J. et al. Journal of Organic Chemistry, 1977 , vol. 42, # 7 p. 1131 - 1133

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Citation Number: 3

Abstract

7-Diben: cobicyclo [2, 2.2] octadienylcarbinyl trifluoromethanesulfonate (1-0Tf) has been acetolyzed and the corresponding amine has been deaminated. The product mixtures, which contain a variety of rearrangement products, have been (analyzed. Paths leading to the products have been considered, and the results are discussed briefly.