Synthetic communications

Synthesis of N-arylhydroxylamines by antimony-catalyzed reduction of nitroarenes

P Ren, T Dong, S Wu

Index: Ren, Pingda; Dong, Tingwei; Wu, Shihui Synthetic Communications, 1997 , vol. 27, # 9 p. 1547 - 1552

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Citation Number: 25

Abstract

Abstract Metallic antimony catalyzes the reduction of aromatic nitro compounds to the corresponding N-arylhydroxylamines in good yields with NaBH4 under mild conditions. The azoxybenzenes from autoxidation of N-arylhydroxylamines were also obtained in basic conditions.

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