Synthesis

Molybdenum (VI) Dichloride Dioxide Catalyzed Synthesis of β-Keto Esters by CH Insertion of Ethyl Diazoacetate into Aldehydes

K Jeyakumar, DK Chand

Index: Jeyakumar, Kandasamy; Chand, Dillip Kumar Synthesis, 2008 , # 11 p. 1685 - 1687

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Citation Number: 13

Abstract

Abstract Synthesis of β-keto esters by condensing various aldehydes with ethyl diazoacetate is achieved by using molybdenum (VI) dichloride dioxide. Aromatic, aliphatic, and heterocyclic aldehydes are successfully condensed with ethyl diazoacetate to obtain corresponding β-keto esters in high yields at room temperature.

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