Tetrahedron letters

Facile N-tert-butoxycarbonylation of amines using La (NO 3) 3· 6H 2 O as a mild and efficient catalyst under solvent-free conditions

…, P Prabhakar, TS Reddy, K Rajesh, Y Venkateswarlu

Index: Suryakiran; Prabhakar; Reddy, T. Srikanth; Rajesh; Venkateswarlu Tetrahedron Letters, 2006 , vol. 47, # 46 p. 8039 - 8042

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Citation Number: 44

Abstract

Facile N-tert-butoxycarbonylation of amines is described by the treatment of various primary, secondary, benzylic and aryl amines with di-tert-butyl dicarbonate in the presence of catalytic amounts of La (NO3) 3· 6H2O under solvent-free conditions at room temperature to afford N-tert-butylcarbamates in excellent yields.

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