Syntheses and lipophilicities of tetraarylborate ions substituted with many trifluoromethyl groups

K Fujiki, M Kashiwagi, H Miyamoto, A Sonoda…

Index: Fujiki, Kanji; Kashiwagi, Mitsuyoshi; Miyamoto, Hideyuki; Sonoda, Akinari; Ichikawa, Junji; et al. Journal of Fluorine Chemistry, 1992 , vol. 57, p. 307 - 321

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Citation Number: 28

Abstract

Abstract Syntheses were investigated using various tetraarylborate ions with a large number of trifluoromethyl groups: tetrakis [3, 5-bis (trifluoromethyl) phenyl] borate; tetrakis [3, 5-bis (1- methoxy-2, 2, 2-trifluoro-1-(trifluoromethyl) ethyl) phenyl] borate; tetrakis [3-(1-methoxy-2, 2, 2-trifluoro-1-(trifluoromethyl) ethyl)-5-(trifluoromethyl) phenyl] borate; and tetrakis [3-(2, 2, 2- trifluoro-1-(2, 2, 2-trifluoroethyoxy)-1-(trifluoromethyl) ethyl)-5-(trifluoromethyl) phenyl] ...