UV absorption spectrum, and kinetics and mechanism of the self reaction of CF3CF2O2 radicals in the gas phase at 295 K
J Sehested, T Ellermann, OJ Nielsen…
Index: Sehested; Ellermann; Nielsen International Journal of Chemical Kinetics, 1993 , vol. 25, # 9 p. 701 - 717
Full Text: HTML
Citation Number: 69
Abstract
Abstract The ultraviolet absorption spectrum, kinetics, and mechanism of the self reaction of CF 3 CF 2 O 2 radicals have been studied in the gas phase at 295 K. Two techniques were used; pulse radiolysis UV absorption to measure the spectrum and kinetics, and long-path length FTIR spectroscopy to identify and quantify the reaction products. Absorption cross sections were quantified over the wavelength range 220–270 nm. At 230 nm, σ math ...
Related Articles:
[Christe, Karl O.; Hegge, Joachim; Hoge, Berthold; Haiges, Ralf Angewandte Chemie - International Edition, 2007 , vol. 46, # 32 p. 6155 - 6158]
[Kloeter,G.; Seppelt,K. Journal of the American Chemical Society, 1979 , vol. 101, p. 347 - 349]
[Barone, Stephen B.; Turnipseed, Andrew A.; Ravishankara, A. R. Journal of Physical Chemistry, 1994 , vol. 98, # 17 p. 4602 - 4608]
[Wallington, Timothy J.; Hurley, Michael D.; Schneider, William F.; Sehested, Jens; Nielsen, Ole John Journal of Physical Chemistry, 1993 , vol. 97, # 29 p. 7606 - 7611]
[Wallington, Timothy J.; Hurley, Michael D.; Schneider, William F.; Sehested, Jens; Nielsen, Ole John Journal of Physical Chemistry, 1993 , vol. 97, # 29 p. 7606 - 7611]