Bulletin of the Chemical Society of Japan

Intramolecular interaction between hydroxyl group and π-electrons. XIV. Electronic effect of the substituents on the interaction in 2-hydroxybiphenyls

M Oki, H Iwamura

Index: Oki,M.; Iwamura,H. Bulletin of the Chemical Society of Japan, 1961 , vol. 34, p. 1395 - 1401

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Citation Number: 17

Abstract

Since the observation by Wulf and his coworkers25, it has been occasionally reported that 2- hydroxybiphenyl shows doublet OH stretching band in the infrared absorption spectrum. The phenomenon was explained on the assumption that 2-hydroxybiphenyl would be composed of eis and trans isomers. Such an explanation had been adopted by Pauling35 for the like phenomenon observed in the infrared spectrum of o-chlorophenol. As the «is isomer ...

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