The Journal of Organic Chemistry

1, 4-and 3, 4-Cycloaddition Reactions of 1, 1-Diphenyl-1, 3-butadiene with Tetracyanoethylene

JJ Eisch, GR Husk

Index: Eisch,J.J.; Husk,G.R. Journal of Organic Chemistry, 1966 , vol. 31, p. 589 - 591

Full Text: HTML

Citation Number: 17

Abstract

Current interest in organometallic additions to conjugated dienes and in the allylic rearrangements of the resulting organometallic systems has prompted us to examine the behavior of l, l-dipheny1-1, 3-butadiene (11) toward other electrophilic addends as well. The finding that diisobutylaluminum hydride adds to I1 in a 3, 4 fashion and that the resulting adduct then rearranges to a 1, 4 adduct2 suggested that other electrophiles might show a ...

Related Articles:

Palladium-catalyzed cross-coupling of cyclopropylmethyl N-tosylhydrazones with aromatic bromides: an easy access to multisubstituted 1, 3-butadienes

[Yang, Qin; Chai, Huining; Liu, Tingting; Yu, Zhengkun Tetrahedron Letters, 2013 , vol. 54, # 48 p. 6485 - 6489]

Transition metal promoted reactions. 30. Cyclopropyl anion as an allyl anion synthon. Novel synthesis of butadienes by nickel-catalyzed coupling of cyclopropyl …

[Ng; Luh Journal of the American Chemical Society, 1989 , vol. 111, # 25 p. 9119 - 9121]

Synthesis, Structure, and Reactions of Stable Titanacyclopentanes.

[Mashima, Kazushi; Sakai, Nozomu; Takaya, Hidemasa Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 8 p. 2475 - 2483]

Cyclopropylmethyl palladium species from carbene migratory insertion: New routes to 1, 3-butadienes

[Zhou, Lei; Ye, Fei; Zhang, Yan; Wang, Jianbo Organic Letters, 2012 , vol. 14, # 3 p. 922 - 925]

Organic photochemistry. XI. Photocycloaddition of benzophenone to conjugated dienes

[Barltrop,J.A.; Carless,H.A.J. Journal of the American Chemical Society, 1971 , vol. 93, p. 4794 - 4801]

More Articles...