Gas-phase generation and infrared spectroscopy of metastable NS-SCN molecule

Z Ajji, DY Naima, MN Odeh, AW Allaf

Index: Ajji; Naima; Odeh, Mohammad N.; Allaf, Abdul W. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 1999 , vol. 55, # 9 p. 1753 - 1756

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Citation Number: 11

Abstract

An attempt has been made to generate the metastable thiazyl thiocyanide molecule, NS- SCN, by means of an on-line process from low pressure, gas-phase pyrolysis of thiazyl chloride, NSCl, over heated AgSCN. The products have been characterized by the IR spectra of their vapors; values for ν1 of 2060 cm− 1 (C N stretch), ν2 of 1365 cm− 1 (N S stretch), and for ν3 of 712.6 cm− 1 (C S stretch) were obtained.