Aryl radical additions to aldehydes and oxime ethers: the tandem enediyne-radical cyclization
JW Grissom, D Klingberg
Index: Grissom, Janet Wisniewski; Klingberg, Detlef Journal of Organic Chemistry, 1993 , vol. 58, # 24 p. 6559 - 6564
Full Text: HTML
Citation Number: 40
Abstract
The previously unreported cyclization of aryl radicals onto aldehyde and oxime ether acceptors is described. The aryl radicals were generated from a cyclization of enediyne substrates. The aldehydes 6 and 9 and the oxime ethers 7 and 10 were heated to 190" C in chlorobenzene in the presence of 1, 4-cyclohexadiene as a hydrogen atom source to yield the tandem enediyne-radical cyclization products lla, llb, 14, 21, and 22, and the simple ...
Related Articles:
[Lee, Taekyu; Jones, J. Bryan Journal of the American Chemical Society, 1997 , vol. 119, # 43 p. 10260 - 10268]
[Grissom, Janet Wisniewski; Klingberg, Detlef; Meyenburg, Sabine; Stallman, Brenda L. Journal of Organic Chemistry, 1994 , vol. 59, # 25 p. 7876 - 7888]
[Lee, Taekyu; Jones, J. Bryan Journal of the American Chemical Society, 1997 , vol. 119, # 43 p. 10260 - 10268]
[Grissom, Janet Wisniewski; Klingberg, Detlef; Meyenburg, Sabine; Stallman, Brenda L. Journal of Organic Chemistry, 1994 , vol. 59, # 25 p. 7876 - 7888]
[Grissom, Janet Wisniewski; Klingberg, Detlef; Meyenburg, Sabine; Stallman, Brenda L. Journal of Organic Chemistry, 1994 , vol. 59, # 25 p. 7876 - 7888]