Optical resolution of (±)-1, 2-bis (2-methylphenyl) ethylene-1, 2-diamine as a chiral framework for 2-iminoimidazolidine with 2-methylphenyl pendant and the …

…, W Nakanishi, M Kawahata, K Yamaguchi…

Index: Ryoda, Akemi; Yajima, Nana; Haga, Toyokazu; Kumamoto, Takuya; Nakanishi, Waka; Kawahata, Masatoshi; Yamaguchi, Kentaro; Ishikawa, Tsutomu Journal of Organic Chemistry, 2008 , vol. 73, # 1 p. 133 - 141

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Citation Number: 57

Abstract

(±)-1, 2-Bis (2-methylphenyl) ethylene-1, 2-diamine, prepared from benzil and ammonium acetate, was optically resolved as a chiral framework for 2-(1-benzyl-2-hydroxyethyl) imino- 1, 3-dimethylimidazolidine with 2-methylphenyl pendants at the 4, 5-positions. Catalysis ability of the 1, 3-dimethyl-4, 5-bis (2-methylphenyl) imidazolidine and the related 1, 3- dibenzyl-4, 5-diphenylimidazolidine was examined in the asymmetric Michael reaction of t ...

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