The Journal of Organic Chemistry

Preparation of vinylene diacetate

J Nagasawa, Y Araki, Y Ishido

Index: Nagasawa, Jun-ichi; Araki, Younosuke; Ishido, Yoshiharu Journal of Organic Chemistry, 1981 , vol. 46, # 8 p. 1734 - 1736

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Citation Number: 4

Abstract

10, X= Br, C1 butene (4) 5 by its oxidation with osmium (VII1) oxideso-dium metaperiodate. Treatment of 3 with acetic anhy-dride-triethylamine in the presence of 44dimethyl-amino) pyridine6 afforded 1 (93: 7 mixture of 2 isomer la and E isomer lb)'in 30% overall yield from 4s (Scheme

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