A case of fully diffusion-controlled exothermic triplet excitation transfer

…, PT Shannon, OC Zafiriou, AK Uriarte

Index: Saltiel, Jack; Shannon, Patrick T.; Zafiriou, Oliver C.; Uriarte, Anthony K. Journal of the American Chemical Society, 1980 , vol. 102, # 22 p. 6799 - 6808

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Citation Number: 57

Abstract

Abstract: Conventional flash kinetic spectroscopy has been used to determine rate constants (k, w) for triplet energy transfer from indeno [2, 1-a] indene, a rigid model of trans-stilbene, to azulene as a function of temperature in n-pentane (228-290 K), toluene (228-309 K), acetonitrile (233-308 K), and tert-butyl alcohol (302-342 K). In toluene the plot of koM vs. T/v is linear with a slope somewhat smaller than predicted by the Debye equation for a ...

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