Palladium/Copper??Catalyzed Oxidative C H Alkenylation/N??Dealkylative Carbonylation of Tertiary Anilines

…, H Zhang, B Chen, Y Sha, C Liu, A Lei

Index: Shi, Renyi; Lu, Lijun; Zhang, Hua; Chen, Borui; Sha, Yuchen; Liu, Chao; Lei, Aiwen Angewandte Chemie - International Edition, 2013 , vol. 52, # 40 p. 10582 - 10585

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Citation Number: 42

Abstract

Anilines are valuable commodity chemicals and useful synthetic building blocks for agrochemicals, active pharmaceutical ingredients, and process chemicals. Although anilines have been widely utilized in chemical synthesis, the orthoselective CÀH bond functionalization of anilines still remains an outstanding challenge.[1] During the past decade, Pdcatalyzed aromatic CÀH functionalization to form CÀC and CÀX bonds has ...

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