Tetrahedron

Cyclic-tri (N-methyl-meta-benzamide) s: substituent effects on the bowl-shaped conformation in the crystal and solution states

…, M Matsumura, K Yamaguchi, H Kagechika, A Tanatani

Index: Kakuta, Hiroki; Azumaya, Isao; Masu, Hyuma; Matsumura, Mio; Yamaguchi, Kentaro; Kagechika, Hiroyuki; Tanatani, Aya Tetrahedron, 2010 , vol. 66, # 42 p. 8254 - 8260

Full Text: HTML

Citation Number: 9

Abstract

Cyclic trimers of 3-(N-alkylamino) benzoic acid (calix [3] amides) with various substituents at the meta position of the phenyl rings were synthesized and the effects of the substituents on the crystal structures and energy profiles in solution were examined. The calixamides existed in a syn conformation in the crystal state, and this was also the major conformation in solution, especially in polar solvents. The energy barrier between syn and anti conformers ...

Related Articles:

Synthesis and biological activities of new di-and trimeric quinoline derivatives

[Broch, Sidonie; Heenon, Helne; Debaud, Anne-Laure; Fogeron, Marie-Laure; Bonnefoy-Berard, Nathalie; Anizon, Fabrice; Moreau, Pascale Bioorganic and Medicinal Chemistry, 2010 , vol. 18, # 19 p. 7132 - 7143]

Shape-persistent cyclyne-type azamacrocycles: synthesis, unusual light-emitting characteristics, and specific recognition of the Sb (V) ion

[Tetrahedron Letters, , vol. 44, # 7 p. 1469 - 1472]

Self-assembly of oligothiophene chromophores by m-Calix [3] amide scaffold

[Journal of Organic Chemistry, , vol. 76, # 8 p. 2471 - 2478]

More Articles...