Journal of Organometallic Chemistry

Synthesis and characterization of 10, 11-dihydro-5H-dibenzo [b, f] metallepins of group IV

JY Corey, M Dueber, M Malaidza

Index: Corey, J. Y.; Duebber, M.; Malaidza, M. Journal of Organometallic Chemistry, 1972 , vol. 36, p. 49 - 60

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Citation Number: 23

Abstract

Abstract Direct reaction of 2, 2′-dilithiobibenzyl with (CH 3) 2 MCl 2 or (C 6 H 5) 2 MCl 2 where M Si, Ge, Sn, or Pb results in the formation of 10, 11-dihydro-5H-dibenzo-[b, f] metallepins. The germanium derivaives were successfully converted to 5, 5-dimethyl-and 5, 5-diphenyl-5H-dibenzo [b, f] germepin by bromination followed by dehydrobromination with 1, 5-diazabicyclo [4.3. 0] non-5-ene. Reactions of dihydrodibenzo [b, f] stannepins ...

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