The Journal of Organic Chemistry

The Chemistry of Carbanions. VIII. The Intramolecular Alkylation of Ketyl Radical Anions1

HO House, JJ Riehl, CG Pitt

Index: House,H.O. et al. Journal of Organic Chemistry, 1965 , vol. 30, p. 650 - 653

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Citation Number: 7

Abstract

Consequently, we have been unable to find reaction conditions which permit the desired cyclization reaction (ie., 1+ 4) to predominate over bond cleavage to form acyclic products (eg, 1-t 5). Since available half-wave potential measurements6 suggest that formation of the ketyl 2 should be energetically favored over direct carbon-chlorine bond cleavage (ie., la or lb 3 6), our results imply that the acyclic products 5 isolated have been derived, at least in ...

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