Dependence of catalytic activity of metal-containing particles on degree of ordering rather than on size and shape. Pd and Ni-catalyzed carbon–heteroatom bond …

IV Chistyakov, VP Ananikov

Index: Chistyakov, Igor V.; Ananikov, Valentine P. Mendeleev Communications, 2013 , vol. 23, # 6 p. 337 - 339

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Abstract

–338–influence of support. Morphology of the synthesized nanoparticles was highly sensitive to the nature of metal and chalcogen reagent, as well as to the nature of the second reagent (alkyne) presented in the reaction mixture during self-organization process. Amazingly, a broad variations of morphology of the particles were observed for the metal chalcogenide material composed of the similar M (ER) 2 structural unit. The changes in ...