SNAr, SN2, and aromatic addition processes in the reactions of picryl ethers with nitrogen and carbon bases
M Strauss, R Torres
Index: Strauss, Michael; Torres, Ruben Journal of Organic Chemistry, 1989 , vol. 54, # 4 p. 756 - 760
Full Text: HTML
Citation Number: 9
Abstract
The reactions of methyl, cyclohexyl, and phenyl picryl ethers with diethyl-and triethylamine in chloroform, acetone, and 1, 3-dicarbomethoxyacetone have been studied. A number of different processes were observed, depending on substrate structure. Both amine nitrogen and enolate carbon act as nucleophiles in these reactions. With unhindered picryl ethers like 2, 4, 6-trinitroanisole, dealkylation often occurs via SN~ attack on the methyl group. With ...
Related Articles:
[Crampton, Michael R.; Robotham, Ian A. Journal of Physical Organic Chemistry, 2013 , vol. 26, # 12 p. 1084 - 1089]
[Crampton, Michael R.; Robotham, Ian A. Journal of Physical Organic Chemistry, 2013 , vol. 26, # 12 p. 1084 - 1089]
[Crampton, Michael R.; Robotham, Ian A. Journal of Physical Organic Chemistry, 2013 , vol. 26, # 12 p. 1084 - 1089]
[Crampton, Michael R.; Robotham, Ian A. Journal of Physical Organic Chemistry, 2013 , vol. 26, # 12 p. 1084 - 1089]
[Crampton, Michael R.; Robotham, Ian A. Journal of Physical Organic Chemistry, 2013 , vol. 26, # 12 p. 1084 - 1089]