Journal of the American Chemical Society

Synthesis and hydrolysis of hexakis (imidazolyl) cyclotriphosphazene

HR Allcock, TJ Fuller

Index: Allcock, H. R.; Fuller, T. J. Journal of the American Chemical Society, 1981 , vol. 103, # 9 p. 2250 - 2256

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Citation Number: 55

Abstract

Abstract: The reaction of imidazole with hexachlorwyclotriphosphazene (I) has yielded hexakis (imidazoly1) cyclotriphosphazene (11). Compound I1 has been studied as a model for the analogous linear high polymer which is a prospective biodegradable camer macromolecule. Compound I1 is hydrolytically unstable and decomposes to hydroxyphosphazenes, imidazole, and phosphate in aqueous media. A kinetic analysis of ...

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