A Novel CC Single-Bond Formation Accompanying CO Bond Cleavage by Use of a Ketone, an Alkylating Reagent, and a Low-Valent Vanadium Complex in …

Y Kataoka, H Akiyama, I Makihira…

Index: Kataoka, Yasutaka; Makihira, Isamu; Akiyama, Hiroaki; Tani, Kazuhide Tetrahedron Letters, 1995 , vol. 36, # 36 p. 6495 - 6498

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Citation Number: 7

Abstract

A CC single-bond-forming reaction from ketones with accompanying CO bond cleavage mediated by a RMgBr or RLi-vanadium (II)-O2 system has been accomplished. Different from conventional reductive coupling reactions of ketones such as the McMurry coupling, the

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