Diorganogallium β-Diketonates and Their Lewis Acid-Base Adducts. Crystal and Molecular Structures of Mes2Ga (hfac) and Me2Ga (hfac)⊙ NC5H5

OT Beachley, JR Gardinier, MR Churchill…

Index: Beachley Jr.; Gardinier, James R.; Churchill, Melvyn Rowen; Toomey, Laurence M. Organometallics, 1998 , vol. 17, # 6 p. 1101 - 1108

Full Text: HTML

Citation Number: 17

Abstract

Compounds of the type R 2 Ga(bdk) (R = Me, Et, Mes (mesityl); bdk = 2,4-pentanedionato (acac), 1,1,1-trifluoro-2,4-pentanedionato (tfac), 1,1,1,5,5,5-hexafluoro-2,4-penatedionato (hfac), 2,2,6,6-tetramethyl-3,5-heptanedionato (tmhd)) have been prepared by multiple routes, including hydrocarbon elimination, metathesis, and ligand redistribution reactions, and fully characterized by elemental analyses, cryoscopic molecular weight studies in ...