Organic letters

Oxidative addition of Pd (0) to Ar-SO2R bonds: Heck-type reactions of sulfones

JL Garcia Ruano, J Alemán, CG Paredes

Index: Ruano, Jose Luis Garcia; Aleman, Jose; Paredes, Cristina Garcia Organic Letters, 2006 , vol. 8, # 13 p. 2683 - 2686

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Citation Number: 19

Abstract

Phenyl vinyl sulfones and sulfoxides react with Pd (OAc) 2 to form styryl sulfoxides and sulfones according to the first Mizoroki-Heck reaction reported for these thio derivatives. Only sulfones are able to react by using catalytic amounts of Pd (up to 1 mol%) in the presence of Ag2CO3. 1, 2-Diphenylsulfonyl ethenes, alkynylphenyl sulfones, and other sulfones, less prone to act as acceptors in the Heck-type reactions, can transfer the aryl ...

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