Synlett

On the Way to an Oxidative Hosomi-Sakurai Reaction

C Sabot, B Commare, MA Duceppe, S Nahi…

Index: Sabot, Cyrille; Commare, Bruno; Duceppe, Marc-Alexandre; Nahi, Salima; Guerard, Kimiaka C.; Canesi, Sylvain Synlett, 2008 , # 20 p. 3226 - 3230

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Citation Number: 24

Abstract

Allylation processes are generally recognized as important tools for organic synthesis; one of the most famous is the Hosomi-Sakurai reaction. [¹] This reaction has opened up many new opportunities in synthetic chemistry. Indeed, the allyl moiety is known to be a good precursor of carbonyl. This reaction consists in the addition of mild nucleophiles such as allylsilanes, propargylsilanes, and enol ethers onto electrophilic species activated by Lewis acids. An interesting ...

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