The Reactions of Esters of Amidosulfurous Acid

H Takei, H Shimizu, M Higo, T Mukaiyama

Index: Takei,H. et al. Bulletin of the Chemical Society of Japan, 1968 , vol. 41, p. 1925 - 1928

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Citation Number: 9

Abstract

It was found that benzhydryl dimethylamidosulfite, obtained from N, N, N′, N′- tetramethylsulfurous diamide-phenyl isocyanate adduct and benzhydrol, decomposed to give benzhydryldimethylamine and sulfur dioxide. Similarly, triphenylmethyl and 1, 3- diphenylallyl dimethylamidosulfite gave corresponding tertiary amines when these esters were refluxed in benzene. On the other hand, benzoin dimethylamidosulfite gave benzil, ...

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