Journal of the American Chemical Society

Sulfur Addition with the Aid of Thiophosphoryl Chloride and the Catalysis of Triaryl Thiophosphate Formation

HB Gottlieb

Index: Gottlieb Journal of the American Chemical Society, 54 <1932 748

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Citation Number: 22

Abstract

Thiophosphoryl chloride changed triphenyl phosphite into triphenyl thiophosphate, tri-o- cresyl phosphite into tri-o-cresyl thiophosphate and diphenylmonochlorophosphite into diphenylmonochloro thiophosphate. The method of preparation consisted in mixing equimolecular amounts of organic phosphite and thiophosphoryl chloride, warming the mixture until reaction occurred, which was very violent at the start. It was completed by ...