Organic letters

Cu-Catalyzed C (sp3)–H Bond Activation Reaction for Direct Preparation of Cycloallyl Esters from Cycloalkanes and Aromatic Aldehydes

J Zhao, H Fang, J Han, Y Pan

Index: Zhao, Jincan; Fang, Hong; Han, Jianlin; Pan, Yi Organic Letters, 2014 , vol. 16, # 9 p. 2530 - 2533

Full Text: HTML

Citation Number: 37

Abstract

Cu-catalyzed dehydrogenation–olefination and esterification of C (sp3)–H bonds of cycloalkanes with TBHP as an oxidant has been developed. The reaction involves four C–H bond activations and gives cycloallyl ester products directly from cycloalkanes and aromatic aldehydes.

Related Articles:

Dinuclear vanadium, copper, manganese and titanium complexes containing O, O, N-dichelating ligands: Synthesis, crystal structure and catalytic activity

[Hosseini-Monfared, Hassan; Asghari-Lalami, Nasim; Pazio, Aleksandra; Wozniak, Krzysztof; Janiak, Christoph Inorganica Chimica Acta, 2013 , vol. 406, p. 241 - 250]

Catalytic decomposition of 1, 3-diphenoxybenzene to monomeric cyclic compounds over palladium catalysts supported on acidic activated carbon aerogels

[Park, Hai Woong; Kim, Jeong Kwon; Hong, Ung Gi; Lee, Yoon Jae; Choi, Jung Ho; Bang, Yongju; Song, In Kyu Applied Catalysis A: General, 2013 , vol. 456, p. 59 - 66]

Epoxidation of alkenes with hydrogen peroxide in the presence of molybdenum oxide-tributyltin chloride on charcoal catalysts.

[Itoi, Yasushi; Inoue, Masami; Enomoto, Saburo; Watanabe, Yoshihiro Chemical and Pharmaceutical Bulletin, 1984 , vol. 32, # 2 p. 418 - 423]

Catalytic decomposition of 4-phenoxyphenol over Pd/XCs 2.5 H 0.5 PW 12 O 40/ACA (activated carbon aerogel)-SO 3 H (X= 10–30wt%) catalysts

[Park, Hai Woong; Kim, Jeong Kwon; Hong, Ung Gi; Lee, Yoon Jae; Song, Ji Hwan; Song, In Kyu Applied Catalysis A: General, 2013 , vol. 453, p. 287 - 294]

Catalytic alkane hydroxylation reaction with nickel (II) complexes supported by di-and triphenol ligands

[Nagataki, Takayuki; Itoh, Shinobu Chemistry Letters, 2007 , vol. 36, # 6 p. 748 - 749]

More Articles...