An Iron (III)–Monoamidate Complex Catalyst for Selective Hydroxylation of Alkane C H Bonds with Hydrogen Peroxide

…, K Arakawa, T Funabiki, M Kodera

Index: Hitomi, Yutaka; Arakawa, Kengo; Funabiki, Takuzo; Kodera, Masahito Angewandte Chemie - International Edition, 2012 , vol. 51, # 14 p. 3448 - 3452

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Citation Number: 65

Abstract

Development of catalysts for the selective hydroxylation of inert CÀH bonds is an important research objective.[1–4] Significant progress toward this goal has been made in recent decades by using biologically inspired iron catalysts and hydrogen peroxide.[5–11] H2O2 is the most ideal oxidant from an atom-economy viewpoint, however, it is generally difficult to use as an oxidant for iron-catalyzed selective oxidations because it easily decomposes to ...

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