Stereospecific palladium-promoted oxyamination of alkenes

JE Baeckvall, EE Bjoerkman

Index: Baeckvall, Jan E.; Bjoerkman, Eva E. Journal of Organic Chemistry, 1980 , vol. 45, # 14 p. 2893 - 2898

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Citation Number: 47

Abstract

A method for direct oxyamination of olefins to vicinal amino alcohol derivatives is described. The reaction proceeds via an aminopalladation-oxidation sequence. Terminal olefins give good yields (6040%) whereas internal olefins give lower yields (2MO%). The oxyamination