The Journal of Organic Chemistry

Perhalodioxins and perhalodihydrodioxins

CG Krespan, DA Dixon

Index: Krespan, Carl G.; Dixon, David A. Journal of Organic Chemistry, 1991 , vol. 56, # 12 p. 3915 - 3923

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Citation Number: 11

Abstract

Two perhalo-1, 4-dioxins, representatives of a previously unknown class of compounds, have been synthesized and shown to exhibit unusual reactivity. In particular, reaction with oxygen is spontaneous and exothermic, and radical-catalyzed homopolymerization will proceed through a fluorinated double bond. Representatives of the perhale2, 3-dihydro-1, 4- dioxin class have also been prepared and found to have reactivity in general intermediate ...