Titanium (III) Chloride Mediated Reduction of Dicyanoalkenes.

A Sera, T Tsuzuki, E Satoh, K Itoh

Index: Sera, Akira; Tsuzuki, Toshihiro; Satoh, Eishi; Itoh, Kuniaki Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 11 p. 3068 - 3071

Full Text: HTML

Citation Number: 7

Abstract

The reaction of substituted dicyanoalkenes with aqueous titanium (III) chloride was examined. The dicyanoalkenes, which showed irreversible reduction characteristics on cyclic voltammograms,(typically, 2-cyano-3-phenylpropenenitrile), afforded cyclized and/or uncyclized hydrodimers, while those characterized by reversible reduction behavior,(typically, 2-cyano-3, 3-diphenylpropenenitrile), yielded the corresponding ...

Related Articles:

General approach to cycloalkanone synthesis. Intramolecular alkylation of 2-chloro-1-olefins

[Lansbury,P.T. et al. Journal of the American Chemical Society, 1970 , vol. 92, # 19 p. 5649 - 5657]

General approach to cycloalkanone synthesis. Intramolecular alkylation of 2-chloro-1-olefins

[Lansbury,P.T. et al. Journal of the American Chemical Society, 1970 , vol. 92, # 19 p. 5649 - 5657]

Stereoselective hydrocoupling of cinnamic acid esters by electroreduction: Application to asymmetric synthesis of hydrodimers

[Kise, Naoki; Iitaka, Shumei; Iwasaki, Keisuke; Ueda, Nasuo Journal of Organic Chemistry, 2002 , vol. 67, # 24 p. 8305 - 8315]

Steric effects in five-membered rings—V: Synthesis, properties, configuration and conformation of 3, 3-and 3, 4-diphenylcyclopentanols

[Warshawsky,A.; Fuchs,B. Tetrahedron, 1969 , vol. 25, p. 2633 - 2646]

Stereoselective hydrocoupling of cinnamic acid esters by electroreduction: Application to asymmetric synthesis of hydrodimers

[Kise, Naoki; Iitaka, Shumei; Iwasaki, Keisuke; Ueda, Nasuo Journal of Organic Chemistry, 2002 , vol. 67, # 24 p. 8305 - 8315]

More Articles...