Ruthenium??Catalyzed Oxidative Cyanation of Tertiary Amines with Hydrogen Peroxide and Sodium Cyanide

SI Murahashi, N Komiya, H Terai

Index: Murahashi, Shun-Ichi; Komiya, Naruyoshi; Terai, Hiroyuki Angewandte Chemie - International Edition, 2005 , vol. 44, # 42 p. 6931 - 6933

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Citation Number: 194

Abstract

There has been much interest in the development of clean and environmentally benign methods for the transformation of amines into the corresponding α-functionalized compounds. These compounds have proven to be versatile intermediates and have been widely used in the construction of biologically active nitrogen compounds such as alkaloids.[1] Direct introduction of a substituent at the α position of tertiary amines is ...

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