Novel and versatile synthetic reagent. Monoalkyl esters of tetraalkylphosphorodiamidous acid

JH Hargis, WD Alley

Index: Hargis,J.H.; Alley,W.D. Journal of the American Chemical Society, 1974 , vol. 96, p. 5927 - 5928

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Citation Number: 10

Abstract

probably the hydration product of the minor 2-cis substrate. 2a might have come partly from the major 2-trans substrate by the action of a trans-cis isomerase, as was found in the metabolic course of epoxyfarnesol.* Metabolite 4b, oil,[a] D-6.6'(c 0.2, MeOH), was identified as methyl (1 1S)-truns, truns-lO-oxo-l I-hydroxyhomofarnesoate, which was clearly an oxidation product of 3a at Clo. Terminal oxidation of an allylic carboxylate in 3a gave an ...