The Reaction of Allylbenzene and CoH (CO) 4

…, TM Bockman, JF Garst, RB King

Index: Ungvary, F.; Marko, L.; Bockman, T. M.; Garst, J. F.; King, R. B. Israel Journal of Chemistry, 1986 , vol. 27, p. 262 - 266

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Citation Number: 7

Abstract

Abstract The carbon monoxide uptake in the reaction of allylbenzene with CoH (CO) 4 in n- octane leading to acylcobalt tetracarbonyls and aldehydes is catalyzed by Co 2 (CO) 8. The rate is half order in Co 2 (CO) 8, first order in allylbenzene and shows a complex dependence in CoH (CO) 4 and CO. From kinetic experiments between 15 and 45 C the temperature dependence of the observed rate constant was determined. The complete ...

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