Metalloporphyrin-catalyzed aerobic oxidation of 2-methoxy-4-methylphenol as a route to vanillin

Q Jiang, W Sheng, X Guo, J Tang, C Guo

Index: Jiang, Qing; Sheng, Wenbing; Guo, Xiangdong; Tang, Jie; Guo, Cancheng Journal of Molecular Catalysis A: Chemical, 2013 , vol. 373, p. 121 - 126

Full Text: HTML

Citation Number: 6

Abstract

We report the use of simple metalloporphyrins (T (p-Cl) PPMnCl, T (p-Cl) PPCo, T (p-Cl) PPFeCl, T (p-Cl) PPCu or [T (p-Cl) PPFe] 2O) as a catalyst for the direct oxidation of 2- methoxy-4-methylphenol to vanillin with molecular oxygen under mild conditions. The research results showed that the type of metalloporphyrin used, catalyst loading, temperature, reaction time, the amount of NaOH, solvent, the amount of solvent and the ...

Related Articles:

Deprotection of Homoallyl (hAllyl) Derivatives of Phenols, Alcohols, Acids, and Amines

[Zhou, Yuhan; Gao, Guchao; Li, Hui; Qu, Jingping Tetrahedron Letters, 2008 , vol. 49, # 20 p. 3260 - 3263]

Proton-Coupled Electron Transfer in the Reduction of Arenes by SmI2–Water Complexes

[Kamochi, Yasuko; Kudo, Tadahiro Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 11 p. 3049 - 3054]

Searching for local biocatalysts: Bioreduction of aldehydes using plant roots of the Province of Córdoba (Argentina)

[Salvano, Mario S.; Cantero, Juan J.; Vazquez, Ana M.; Formica, Stella M.; Aimar, Mario L. Journal of Molecular Catalysis B: Enzymatic, 2011 , vol. 71, # 1-2 p. 16 - 21]

Removal of O-and N-benzyl groups by fungal biotransformation

[Holland, Herbert L.; Conn, Morgan; Chenchaiah, P. Chinna; Brown, Frances M. Tetrahedron Letters, 1988 , vol. 29, # 49 p. 6393 - 6394]

Water-Controlled Regioselectivity of Pd-Catalyzed Domino Reaction Involving a C− H Activation Process: Rapid Synthesis of Diverse Carbo-and Heterocyclic …

[Lu, Zhiyao; Hu, Chunmei; Guo, Jiajie; Li, Jing; Cui, Yuxin; Jia, Yanxing Organic Letters, 2010 , vol. 12, # 3 p. 480 - 483]

More Articles...